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Analytical methods applied for the evaluation of environmental contamination by uranium ore mining
Bílek, Jiří ; Holubová, Zuzana (referee) ; Čáslavský, Josef (advisor)
This thesis deals with the testing procedures used in monitoring of environmental contamination after uranium ore mining in the uranium mine in Dolní Rožínka. It deals with the determination of radioactive elements radium, uranium and radon. The methods used for the determination of radioactive elements in mine laboratory in Dolní Rožínka are described. The thesis also mentions other applicable methods for determination of uranium. The metods of determination of manganese, iron and other metallic elements are also summarized in brief.The values of concentrations of monitored analytes in selected locations are presented at the end of the thesis. These values, which were provided by laboratories in Dolní Rožínka, are valid for 2010.
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Determination of radionuclides in water and sediments
Bílek, Jiří ; Holubová, Zuzana (referee) ; Komendová, Renata (advisor)
This thesis has been prepared for DIAMO, Branch GEAM Dolní Rožínka. Literature research includes a description of the ionizing radiation, natural radionuclides, mining of uranium ore and mineral deposits; Běstvina and Licoměřice. The experimental part includes sampling, analysis and evaluation of the content of selected radionuclides in the two selected locations. The content of uranium and radium in sludge from mine water treatment plant is determined annually by an external laboratory, using of semiconductor gamma-spectrometric analysis (GSA). Determination of both radionuclides in waters in these areas is carried out in the Centre of testing laboratories (SZLAB) in Dolní Rožínka. Uranium and radium activity is below the detection limit. Sludges from Běstvina, according to the results of external laboratories, routinely show activity of both radionuclides. But activity in the waters from this locality is below the detection limit. The goal of this diploma thesis is to verify the radionuclide content in sludge from CDV Běstvina by another method. As a comparative method was chosen determination of uranium using the UV-VIS spectrophotometry with separation on silicagel. Location Licoměřice was chosen as a reference. Like a supplementary method for determining the concentration of uranium was chosen ICP-MS. For the determination of the radium was chosen radiochemical method scintillator ZnS (Ag).
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Historical use of waste from the Jáchymov uranium factory as a building material
Voháňková, Michaela ; Goliáš, Viktor (advisor) ; Šálek, Ondřej (referee)
Between 1853 and 1939, colourful and highly sought-after uranium paints were produced on an industrial scale in Jáchymov. Until the discovery of radium by Marie Curie Skłodowska in 1898, the waste from production was considered essentially worthless. In the 1970s, the use of materials with increased radioactivity was detected in buildings in Jáchymov. Some of the most affected buildings were demolished. In the 1990s, remediation interventions took place during which these building materials (plaster and mortar) were removed from most of the buildings. During this period, gamma radiation doses as well as radioactivity and uranium were measured in the laboratory. The mineralogical and phase character of the material was not investigated, which was the main objective for this bachelor thesis. The presumption of preservation of at least some of the surviving houses was minimal. Nevertheless, a few unique cases have been found. A total of 11 buildings were found along a 12 km tour whose plaster showed elevated radioactivity ranging from 3.2 to 28.4 μGy/h. Sampling was carried out at 6 of them. Determination of 226 Ra mass activities was performed by laboratory gamma spectrometry, uranium contents were determined by instrumental neutron activation analysis. In the study set, the radium activities reached...
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Why Mrs. Curie did not die from acute radiation sickness?
VOTRUBOVÁ, Jitka
This thesis deals with the scientific achievements of the inspirational scientist Marie Curie Sklodowska as well as with the issue of acute iradiation sickness. Two goals were set in the work. The first objective was to map the life and scientific work of Mrs. Curie. The second objective was to describe the causes and consequences of acute illness from radiation. At the beginning the theoretical part describes the life of Marie Curie Sklodowska. Her difficult beginnings at the University of Paris and her great achievements- discovering the elements of polonium and radium. Further, the work deals with acute radiation sickness together with basics of radiobiology. In the practical part, I tried to find an answer to this question. Why Mrs. Curie did not die from acute radiation sickness? I have gained a lot of information by studying literature, professional articles and internet resources. Most of the facts were obtained from foreign professional journals because there are not many sources in the Czech language. Thanks to this information, I could deal with this person more detailed. At the same time, in the case of toxic polonium-210, an estimated fatal dose for adults was calculated. In addition, calculations were made of how much Marie Curie Sklodowska would have to isolate and incorporate in order to die for the consequences of acute radiation sickness. For better clarity, the results are summarized in the tables. Safety precautions and health problems associated with work with radioactive elements would not be neglected. Marie Curie Sklodowska probably was not able to create a clean polonium, and therefore probably did not even accept this direct contact, which would be able to cause her death.
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Contamination of floodplain of the Ploucnice by heavy metals: relation to its architecture
Hošek, Michal ; Goliáš, Viktor (advisor) ; Kříbek, Bohdan (referee)
Summary: This thesis is focused on mapping of contaminants released into the environment probably due to uranium mining. These chemical contaminants are used to reconstruct the sedimentary processes. The aim of the thesis was both the geochemical assessment of the situation in the catchment area of the Ploucnice River in Boreček using the flood sediments from the research points as sedimentary archives pollution for last decades. With depth profiles, gamma wire log, XRF and enrichment factors (LEF), we have tried to perform chemostratigraphic correlation of the sediments. As target elements U, Ba, Zn and Ni were chosen, whose concentrations are related to the grain size of the sediment. Furthermore, the theory of secondary pollution is developed.
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Contamination of foodplain of the Ploučnice river by heavy metals: relation to its architecture
Hošek, Michal ; Goliáš, Viktor (advisor) ; Kříbek, Bohdan (referee)
Summary: This thesis is focused on mapping of contaminants released into the environment probably due to uranium mining. These chemical contaminants are used to reconstruct the sedimentary processes. In the thesis we evaluate geochemical situation in the catchment area in the locality Borecek (part of the municipality Ralsko) using the overbank sediments as sedimentary archives of pollution during the last decades by elements U, Ba, Zn, Ni and 226 Ra. A map of aerial survey of gamma activity was used to select the area of interest, for more accurate localisation we used a surface gamma spectrometry. On Borecek we retrieved ten depth profiles of alluvial sediments (up to 230 cm) and one in Mimon, all samples were subjected to X-ray fluorescence spectral analysis (XRF), across the floodplain we performed gamma wire logs. For interpretations of floodplains architecture electrical resistivity tomography (ERT) was used and selected profiles were analysed for the activity of 226 Ra and 210 Pb. Interrelation of 226 Ra and Ba proved that radiobarite is the main source of the gamma activity. 210 Pb / 226 Ra ratio was used as sediment age indicator. With enrichment factor (LEF), we performed chemostratigraphic correlation of the sediments, for that the concentration of the target elements is corrected for varying...
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Mineralogical speciation of the radium isotopes in Karlovy Vary hot spring sediments: Results of the selective dissolution
Supiňková, Taťána ; Goliáš, Viktor (advisor) ; Smrček, Stanislav (referee)
Thermal waters in Karlovy Vary are characterized by carbonate sedimentation in places of their emergence. These sediments contain radium. Radium bond in every type of sinter (aragonite, calcite) has been investigated experimentally by acid sinter dissolution. It has been found out, that radium can join dissoluble fraction in both sinter types . The original hypothesis that radium can bond only aragonite-type of sinter has been refuted. Additional experiments have been processed using synthetic radiobarite. Present radium in radiobarite can be partly dissoluted using acids. If radium was incorporated in radiobarite (it is known from locality Vřídlo in Karlovy Vary and elsewhere) then maybe it would be partly dissoluted in experiments.
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Determination of radionuclides in water and sediments
Bílek, Jiří ; Holubová, Zuzana (referee) ; Komendová, Renata (advisor)
This thesis has been prepared for DIAMO, Branch GEAM Dolní Rožínka. Literature research includes a description of the ionizing radiation, natural radionuclides, mining of uranium ore and mineral deposits; Běstvina and Licoměřice. The experimental part includes sampling, analysis and evaluation of the content of selected radionuclides in the two selected locations. The content of uranium and radium in sludge from mine water treatment plant is determined annually by an external laboratory, using of semiconductor gamma-spectrometric analysis (GSA). Determination of both radionuclides in waters in these areas is carried out in the Centre of testing laboratories (SZLAB) in Dolní Rožínka. Uranium and radium activity is below the detection limit. Sludges from Běstvina, according to the results of external laboratories, routinely show activity of both radionuclides. But activity in the waters from this locality is below the detection limit. The goal of this diploma thesis is to verify the radionuclide content in sludge from CDV Běstvina by another method. As a comparative method was chosen determination of uranium using the UV-VIS spectrophotometry with separation on silicagel. Location Licoměřice was chosen as a reference. Like a supplementary method for determining the concentration of uranium was chosen ICP-MS. For the determination of the radium was chosen radiochemical method scintillator ZnS (Ag).
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Analytical methods applied for the evaluation of environmental contamination by uranium ore mining
Bílek, Jiří ; Holubová, Zuzana (referee) ; Čáslavský, Josef (advisor)
This thesis deals with the testing procedures used in monitoring of environmental contamination after uranium ore mining in the uranium mine in Dolní Rožínka. It deals with the determination of radioactive elements radium, uranium and radon. The methods used for the determination of radioactive elements in mine laboratory in Dolní Rožínka are described. The thesis also mentions other applicable methods for determination of uranium. The metods of determination of manganese, iron and other metallic elements are also summarized in brief.The values of concentrations of monitored analytes in selected locations are presented at the end of the thesis. These values, which were provided by laboratories in Dolní Rožínka, are valid for 2010.
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Protection of workers, inhabitants and environment during mining and processing of uranium ore
PILECKÁ, Eliška
In the Czech republic uranium had been mined in Jáchymov (till 1967), near Příbram (1948 {--} 1991), in Okrouhlá Radouň in the south of Bohemia (1972 {--} 1990), near Vítkov in the west of Bohemia (till 1991), in Zadní Chodov (till 1992), in Dyleň (till 1994), in Hamr and Křížany near Stráž under Ralsko (till 1990), in Zálesí in Rychlebské Mountain and in many other locations. The mining of uranium influenced in considerable way health and quality of miners´ lives, and also lives of their relatives and up to now it still influencing quality of lives of people living near mining locations. Above all the uranium industry made irreparable changes in our country and the leftovers are up to now influencing the quality of our environment. That´s why there is a must to pay special attention to this area. Nowadays in the Czech republic there is registered around 3768 old uranium mines, out of it there is 2523 mining cannons which are obliged to be regularly controlled. The negative influences are marked as old burdens of already eliminated mining or modificating act on our environment or in some other way threatening public interests. According to the character of negative expression we distinguish mining burdens, it means negative influence of mining activity on stableness of the surface, and ecological burdens, it means negative influence on our environment. In my opinion a matter of uranium industry is very rarely known to the wide public. The main reason why is it like this can be the fact that in the period of main expansion of uranium industry in the Czech republic all the information connected to the research, mining or maintaining of uranium, were top secret. The second reason can be no existence of complete source of information that could be used for study purposes and the same time for informing general public. That is why this study should purvey such source.
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